Supervised Work

Supervised Work

41. Baran, P. S.; Guerrero, C. A.; Corey, E. J. The First Method for Protection-Deprotection of the Indole 2,3-π Bond, Org. Lett. 2003, 5, 1999 – 2001.
40. Baran, P. S.; Guerrero, C. A.; Corey, E. J. A Short, Enantioselective Total Synthesis of Okaramine N, J. Am. Chem. Soc. 2003, 125, 5628 – 5629.
39. Nicolaou, K.C.; Baran, P.S. The CP-Molecules Labyrinth: How Endeavors in Total Synthesis Lead to Discoveries and Inventions in Organic Synthesis, Angew. Chem. Int. Ed. 2002, 41, 2678 – 2720.
38. Baran, P. S.; Corey, E. J. A Short Synthetic Route to (+)-Austamide, (+)-Deoxyaustamide, and (+)-Deoxyisoaustamide from a Common Preecursor by a Novel Palldium-Mediated Indole to Dihydroindoloazocine Cyclization, J. Am. Chem. Soc. 2002, 124, 7904 – 7905.
37. Nicolaou, K.C.; Montagnon, T.; Baran, P.S. HIO3 and I2O5: Mild and Selective Alternatives Reagents to IBX for the Dehydrogenation of Aldehydes and Ketones, Angew. Chem. Int. Ed. 2002, 41, 1386-1389.
36. Nicolaou, K.C.; Montagnon, T.; Baran, P.S. Modulation of the Reactivity Profile of IBX by Ligand Complexation: Ambient Temperature Dehydrogenation of Aldehydes and Ketones to a,b-Unsaturated Carbonyl Compounds, Angew. Chem. Int. Ed. 2002, 41, 993 – 996.
35. Nicolaou, K.C.; Jung, J.; Yoon, W. H.; Fong, K. C.; Choi, H. ¡VS.; He, Y.; Zhong, Y. L.; Baran, P. S. Total Synthesis of the CP-Molecules (CP-263,114 and CP-225,917, Phomoidrides B and A). Part 1. Racemic and Asymmetric Synthesis of Bicyclo(4.3.1) Key Building Blocks, J. Am. Chem. Soc. 2002, 124, 2183 – 2189.
34. Nicolaou, K.C.; Baran, P. S., Zhong, Y. L.; Fong, K. C.; Choi, H. ¡VS. Total Synthesis of the CP-Molecules (CP-263,114 and CP-225,917, Phomoidrides B and A). Part 2. Model Studies for the Construction of Key Structural Elements and First Generation Strategy, J. Am. Chem. Soc. 2002, 124, 2190 – 2201.
33. Nicolaou, K.C.; Zhong, Y. L.; Baran, P. S.; Jung, J.; Choi, H. ¡VS.; Yoon, W. H. Total Synthesis of the CP-Molecules (CP-263,114 and CP-225,917, Phomoidrides B and A). Part 3. Completion and Synthesis of Advanced Analogs, J. Am. Chem. Soc. 2002, 124, 2202 – 2211.
32. Nicolaou, K.C.; Baran, P. S.; Zhong, Y. L.; Sugita, K. Iodine(V)-Reagents in Organic Synthesis. Part 1. Synthesis of Polycyclic Heterocycles via DMP-Mediated Cascade Cyclization: Generality, Scope and Mechanism of the Reaction, J. Am. Chem. Soc. 2002, 124, 2212 – 2220.
31. Nicolaou, K.C.; Sugita, K.; Baran, P. S.; Zhong, Y. L. Iodine (V)-Reagents in Organic Synthesis. Part 2. Access to Complex Molecular Architectures via DMP-Generated o-Imidoquinones, J. Am. Chem. Soc. 2002, 124, 2221 – 2232.
30. Nicolaou, K.C.; Baran, P. S.; Zhong, Y. L.; Barluenga, S.; Hunt, K. W.; Kranich, R.; Vega, J. A. Iodine(V) Reagents in Organic Synthesis. Part 3. New Routes to Heterocyclic Compounds via IBX-Mediated Cyclizations: Generality, Scope, and Mechanism, J. Am. Chem. Soc. 2002, 124, 2233 – 2244.
29. Nicolaou, K.C.; Montagnon, T.; Baran, P. S.; Zhong, Y. L. Iodine(V)-Reagents in Organic Synthesis. Part 4. IBX as a Chemospecific Tool for SET-Based Oxidation Processes, J. Am. Chem. Soc. 2002, 124, 2245 – 2258.
28. Nicolaou, K.C.; Montagnon, T.; Ulven, T.; Baran, P. S.; Zhong, Y. L.; Sarabia, F. Novel Chemistry of £\-Sulfonated Ketones: Applications to the Solution and Solid Phase Synthesis of Privileged Heterocycle and Enediyne Libraries, J. Am. Chem. Soc. 2002, 124, 5718 – 5728.
27. MacMahon, S.; Fong, R.; Baran, P.S.; Safonov, I.; Wilson, S.R.; Schuster, D.I. Synthetic Approaches to a Variety of Covalently Linked Porphyrin-Fullerene Hybrids J. Org. Chem. 2001, 66; 5449-5455.
26. Nicolaou, K.C.; Baran, P.S.; Zhong, Y.L. Selective Oxidation at Carbon Adjacent to Aromatic Systems with IBX, J. Am. Chem. Soc. 2001, 123, 3183 – 3185.
25. Nicolaou, K.C.; Zhong, Y. L.; Baran, P.S.; Sugita, K. Rapid Access to Molecular Complexity via o-Azaquinones, Angew. Chem. Int. Ed. 2001, 40, 2145.
24. Wilson, S.R.; Baran, Phil S.; Schuster, D.I.; Goh, S.K.; Marynick, D.S. Theoretical and Experimental Studies of Fullerene and Nanotube Arene-chromium Complexes, manuscript in preparation.
23. Nicolaou, K.C.; Sugita, K.; Baran, P.S; Zhong, Y.-L. New Synthetic Technology for the Synthesis of Quinones Using DMP, Angew. Chem. Int. Ed. 2001, 40, 207-210.
22. Nicolaou, K.C.; Baran, P.S.; Kranich, R.; Zhong, Y.L.; Sugita, K.; Zou, N.; Mechanistic Studies of the Interactions of Periodinane Reagents with Anilides, Angew. Chem. Int. Ed. 2001, 40, 202-206.
21. Nicolaou, K.C.; Vourloumis, D.; Winssinger, N.; Baran, P.S. The Art and Science of Total Synthesis at the Dawn of the Twenty-first Century, Angew. Chem. Int. Ed. 2000, 39,44-122.
20. Nicolaou, K.C.; Baran, P.S.; Zhong, Y.L. Novel Solution and Solid Phase Chemistry of a-Sulfonated Ketones Applicable to Combinatorial Chemistry, J. Am. Chem. Soc. 2000, 122, 10246-10248.
19. Nicolaou, K.C.; Zhong, Y.-L.; Baran, Phil S. A New One-step Method for the Oxidation of Alcohols and Carbonyl Compounds to a,b-Unsaturated Systems, J. Am. Chem. Soc. 2000, 122, 7596-7597.
18. Nicolaou, K.C.; Baran, P.S.; Zhong, Y.-L.; Vega, J.A. Novel IBX-mediated Processes for the Synthesis of Amino Sugars and Libraries Thereof, Angew. Chem. Int. Ed. 2000, 39, 2525-2529.
17. Nicolaou, K.C.; Jung, J.-K.; Yoon, W.-Y.; He, Y.; Zhong, Y.-L.; Baran, P.S. The Absolute Configuration and Total Synthesis of the CP-molecules, Angew. Chem. Int. Ed. 2000, 39, 1829-1832.
16. Nicolaou, K.C.; Vassilikogiannakis, G.; Kranich, R.; Baran, P.S.; Zhong, Y.L.; Natarajan, S. New Synthetic Technology for the Mild and Selective Homologation of Hindered Aldehydes in the Presence of Ketones, Org. Lett. 2000, 2, 1895-1898.
15. Nicolaou, K.C.; Vassilikogiannakis, G.; Simonsen, K.B.; Baran, P.S.; Zhong, Y.-L.; Vidali, V.P.; Pitsinos, E.N.; Couladouros, E.A. Biomimetic Total Synthesis of Bisorbicillinol, Bisorbibutenolide, Trichodimerol and Designed Analogs of the Bisorbicillinoids, J. Am. Chem. Soc. 2000, 122, 3071 – 3079.
14. Baran, P.S.; Khan, A.U.; Schuster, D.I. Some Photophysical Properties of Nanotubes, Fullerene Sci. Tech. 1999, 7, 921-925.
13. Nicolaou, K.C.; Zhong, Y.-L.; Baran, P.S. New Synthetic Technology for the Rapid Construction of Novel Heterocycles. 1. The Reaction of Dess-Martin Periodinane with Anilides and Related Compounds, Angew. Chem. Int. Ed. 2000, 39, 622-625.
12. Nicolaou, K.C.; Zhong, Y.-L.; Baran, P.S. New Synthetic Technology for the Rapid Construction of Novel Heterocycles. 2. The Reaction of IBX with Anilides and Related Compounds, Angew. Chem. Int. Ed. 2000, 39, 625-628.
11. Nicolaou, K.C.; Jautelat, R.; Vassilikogiannakis, G.; Baran, P.S.; Simonsen, K. Studies towards Trichodimerol: Novel Cascade Reactions and Polycyclic Frameworks, Chem. Eur. J. 1999, 5, 3651-3665.
10. Nicolaou, K.C.; Simonsen, K.S.; Vassilikogiannakis, G.; Baran, P.S.; Vidali, V.P.; Pitsinos, E.N.; Couladouros, E.A. Biomimetic Explorations Towards the Bisorbicillinoids. Total Synthesis of Bisorbicillinol, Bisorbibutenolide and Trichodimerol, Angew. Chem. Int. Ed. 1999, 38, 3555-3559.
9. Nicolaou, K.C.; Baran, P.S.; Zhong, Y.-L.; Choi, H.-S.; Fong, K.C.; He, Y.; Yoon, W.H. New Synthetic Technology for the Synthesis of Hindered a-Diazoketones via Acyl Mesylates, Org. Lett. 1999, 1, 883-886.
8. Nicolaou, K.C.; Baran, P.S.; Zhong, Y.-L.; Choi, H.-S.; Yoon, W.H.; He, Y.; Fong, K.C. Total synthesis of the CP molecules CP-263,114 and CP-225,917- Part 1: Synthesis of Key Intermediates and Intelligence Gathering, Angew. Chem. Int. Ed. 1999, 38, 1669-1675.
7. Nicolaou, K.C.; Baran, P.S.; Zhong, Y.-L.; Fong, K.C.; He, Y.; Yoon, W.H.; Choi, H.S. Total Synthesis of the CP Molecules CP-263,114 and CP-225,917- Part 2: Evolution of the Final Strategy Angew. Chem. Int. Ed. 1999, 38, 1676-1678.
6. Nicolaou, K.C.; He, Y.; Fong, K.C.; Yoon, W.H.; Choi, H.-S.; Zhong, Y.-L.; Baran, P.S. Novel Strategies to Construct the g-Hydroxy Lactone Moiety of the CP Molecules. Synthesis of the CP-225,917 Core Skeleton. Org. Lett. 1999, 1, 63-66.
5. Nicolaou, K.C.; Baran, P.S.; Jautelat, R.; He, Y.; Fong, K.C.; Choi, H.-S.; Yoon, W.H.; Zhong, Y.-L. A Novel Route to the Fused Maleic Anhydride Moiety of CP Molecules. Angew. Chem. Int. Ed. 1999, 38, 549-552.
4. Schuster, D.I.; Baran, P.S.; Hatch, R.K.; Khan, A.U.; Wilson, S.R. The Role of Singlet Oxygen in the Photochemical Formation of C60O, Chem. Commun. (Cambridge) 1998, 22, 2493-2494.
3. Safonov, I.G.; Baran, P.S.; Schuster, D.I. Synthesis and Photophysics of a Novel Porphyrin-C60 Hybrid, Tetrahedron Lett. 1997, 38, 8133-8136.
2. Baran, P.S.; Monaco, R.R.; Khan, A.U.; Schuster, D.I.; Wilson, S.R. Synthesis and Cation-mediated Electronic Interactions of Two Novel Classes of Porphyrin-fullerene Hybrids, J. Am. Chem. Soc. 1997, 119, 8363-8364.
1. Baran, P.S.; Monaco, R.R.; Khan, A.U.; Schuster, D.I.; Soulas, P.; Echegoyen, L. Synthesis and Cation-mediated Electronic Interactions of Two Novel Classes of Porphyrin-fullerene Hybrids. Proc. – Electrochem. Soc. 1997, 97-14 (Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials), 25-36.