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    is total synthesis here to stay?
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  • choose your method wisely...
    The Race 2.0
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    Mole Scale decarboxylative alkenylation
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    decarboxylative borylation
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    the portable chemist's consultant
  • 70 years in the making
    Phil alkylates biotin
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    IKA's The Race - Part I
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    IKA's The Race - Part II
  • Using an exotic solvent...
    Phil runs a reductive olefin coupling
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Fresh from the ASAPs

Full publications list
  • FULL TEXT
    198. Kingston, C.; Wallace, M; Allentoff, A. J.; deGruyter, J.; Chen, J.; Gong, S.; Bonacorsi, S. Jr.; Baran, P. S. Direct Carbon Isotope Exchange Through Decarboxylative Carboxylation. ChemRxiv preprint, 2018.
  • FULL TEXT
    197. Smith, J.; Dixon, J.; deGruyter, J. N.; Baran, P. S. Alkyl Sulfinates: Radical Precursors Enabling Drug Discovery. J. Med. Chem. ASAPs.
  • FULL TEXT
    SUPPORTING INFORMATION
    196. Ni, S.; Garrido-Castro, A. F.; Merchant, R. R.; deGruyter, J. N.; Schmitt, D. C.; Mousseau, J. J.; Gallego, G. M.; Yang, S.; Collins, M. R.; Qiao, J. X.; Yeung, K.; Langley, D. R.; Poss, M. A.; Scola, P. M.; Qin, T.; Baran, P. S. A General Amino Acid Synthesis Enabled by Innate Radical Cross-Coupling, Angew. Chem. Int. Ed. 10.1002/anie.201809310
  • FULL TEXT
    SUPPORTING INFORMATION
    195. Wang, J.; Shang, M.; Lundberg, H.; Feu, K. S.; Hecker, S. J.; Qin, T.; Blackmond, D. G.; Baran, P. S. Cu-Catalyzed Decarboxylative Borylation. ACS Catal. 2018, ASAPs.
  • FULL TEXT
    Blog post
    SUPPORTING INFORMATION
    194. Knouse, K. W.; deGruyter, J. N.; Schmidt, M. A.; Zheng, B.; Vantourout, J. C.; Kingston, C.; Mercer, S. E.; Mcdonald, I. M.; Olson, R. E.; Zhu, Y.; Hang, C.; Zhu, J.; Yuan, C.; Wang, Q.; Park, P.; Eastgate, M. D.; Baran, P. S. Unlocking P(V): Reagents for chiral phosphorothioate synthesis. Science First Release.
  • FULL TEXT
    193. Smith, J. M.; Harwood, S. J.; Baran, P. S. Radical Retrosynthesis. Acc. Chem. Res. ASAPs.
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