Baran Lab

Synthesis in the Age of Scalability

Translational Methods

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the race 3.0
is total synthesis here to stay?

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ElectraSyn 2.0

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The Race 2.0

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Mole Scale decarboxylative alkenylation

We're gonna need a bigger bucket
decarboxylative borylation

how would yu do it?
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consulting, on a budget
Phil alkylates biotin

70 years in the making
IKA's The Race - Part I

Phil and Jin face-off in a high speed duel
IKA's The Race - Part II

Looks like someone's been lifting
Phil runs a reductive olefin coupling

Using an exotic solvent...
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Full publications list

FULL TEXT

227. Gnaim, S.; Vantourout, J. C.; Serpier, F.; Echeverria, P.-G.; Baran, P. S. Carbonyl Desaturation: Where Does Catalysis Stand? ACS Catal. 2021, Just Accepted
FULL TEXT

SUPPORTING INFORMATION

226. Hu, P.; Peters, B. K.; Malapit, C. A.; Vantourout, J. C.; Wang, P.; Li, J.; Mele, L.; Echeverria, P.-G.; Minteer, S. D.; Baran, P. S. Electroreductive Olefin-Ketone Coupling. J. Am. Chem. Soc. 2020 Just Accepted
FULL TEXT

225. Zhao, J.-X.; Chang, Y.; Elleraas, J.; Montgomery, T. P.; Spangler, J. E.; Nair, S. K.; Bel, D. M.; Gallego, G. M.; Mousseau, J. J.; Perry, M. A.; Collins, M. R.; Vantourout, J. C.; Baran, P. S. 1,2-Difunctionalized Bicyclo[1.1.1]pentanes: Long Sought After Bioisosteres for ortho/meta-Substituted Arenes. ChemRxiv Preprint 2020
FULL TEXT

224. Vantourout, J. C.; Adusumalli, S. R.; Knouse, K. W.; Flood, D. T.; Ramirez, A.; Padial, N. M.; Istrate, A.; Maziarz, K.; deGruyter, J. N.; Merchant, R. R.; Qiao, J. X.; Schmidt, M. A.; Deery, M. J.; Eastgate, M. D.; Dawson, P. E.; Bernardes, G. J. L.; Baran, P. S. Serine-Selective Bioconjugation. J. Am. Chem. Soc. 2020 Just Accepted
FULL TEXT

223. Sheng, T.; Zhang, H.-J.; Shang, M.; He, C.; Vantourout, J. C.; Baran, P. S. Electrochemical Decarboxylative N‑Alkylation of Heterocycles. Org. Lett. 2020, 22, 7594-7598
FULL TEXT

222. Chen. L.; Barton, L. M.; Vantourout, J. V.; Xu, Y.; Chu, C.; Johnson, E. C.; Sabatini, J. J.; Baran, P. S. Electrochemical Cyclobutane Synthesis in Flow: Scaleup of a Promising Melt-Castable Energetic Intermediate. Org. Process. Res. Dev. 2020 Just Accepted
FULL TEXT

221. He, C.; Chu, H.; Stratton, T. P.; Kossler, D.; Eberle, K. J.; Flood, D. T.; Baran, P. S. Total Synthesis of Tagetitoxin, J. Am. Chem. Soc. 2020, 142, 13683-13688

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