250. He, C.; Wang, Y.; Bi, C.; Peters, D. S.; Gallagher, T. J.; Teske, J.; Chen, J. S.; Corsetti, R.; D'Onofrio, A.; Lewis, K.; Baran, P. S. Total Synthesis of Kibdelomycin. Angew. Chemie. Int. Ed. 2022, Just Accepted
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249. Laudadio, G.; Palkowitz, M. D.; Ewing, T. E.-H.; Baran, P. S. Decarboxylative Cross-Coupling: A Radical Tool In Medicinal Chemistry. ChemRxiv Preprint 2022 -
248. Lou, T. S.-B.; Kawamata, Y.; Ewing, T.; Correa-Otero, G. A.; Collins, M. R.; Baran, P. S. Scalable, Chemoselective Ni-Electrocatalytic Sulfinylation of Aryl Halides with SO2, ChemRxiv Preprint 2022
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247. Lin, Y.-C.; Schneider, F.; Eberle, K, J.; Chiodi, D.; Nakamura, H.; Reisberg, S. H.; Chen, J.; Saito, M.; Baran, P. S. Atroposelective Total Synthesis of Darobactin A. J. Am. Chem. Soc. 2022. Just Accepted
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246. Palkowitz, M. D., Laudadio, G.; Kolb, S.; Choi, J.; Oderinde, M. S.; Ewing, T. E.-H.; Bolduc, P.; Chen, T.; Zhang, H.; Cheng, P. T. W.; Zhang, B.; Mandler, M.; Richter, J. M.; Collins, M. R.; Schioldager, R. L.; T. G. M. Dhar; Vokits, B.; Zhu, Y.; Echeverria, P.-G.; Poss, M. A.; Shaw, S.; Clementson, S.; Petersen, N. N.; Mykhailiuk, P.; Baran, P. S. Overcoming Limitations in Decarboxylative Arylation via Ag-Ni Electrocatalysis. ChemRxiv Preprint 2022
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245. Gao, Y.; Zhang, B.; Levy, L.; Zhang, H. -J.; He, C.; Baran, P. S. Ni-Catalyzed Enantioselective Dialkyl Carbinol Synthesis via Decarboxylative Cross Coupling: Development, Scope, and Applications. J. Am. Chem. Soc. 2022 Just Accepted
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244. Hayashi, K.; Griffin, J.; Harper, K. C.; Kawamata, Y.; Baran, P. S. Chemoselective, Metal-free, (Hetero)Arene Electroreduction Enabled by Rapid Alternating Polarity. J. Am. Chem. Soc. 2022 Just Accepted
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243. Kawamata, Y.; Ryu, K. A.; Hermann, G. N.; Sandahl, A.; Vantourout, J. C.; Olow, A. K.; Adams, L.-T., A.; Rivera-Chao, E.; Roberts, L. R.; Oslund, R. C.; Fadeyi, O. O.; Baran, P. S. Electroaffinity Labeling: A New Platform for Chemoproteomic-based Target Identification. ChemRxiv Preprint 2022
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242. Zhang, B.; Gao, Y.; Hioki, Y.; Oderinde, M. S.; Qiao, J. X.; Rodriguez, K. X.; Zhang, H.-J.; Kawmata, Y.; Baran, P. S. Ni-Electrocatalytic C(sp3 )–C(sp3 ) Doubly Decarboxylative Coupling. Nature, 2022, Just Accepted
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241. Gu, J.; Rodriguez, K. X.; Kanda, Y.; Yang, S.; Ociepa, M.; Wilke, H.; Abrishami, A. V.; Jørgensen, L.; Skak-Nielsen, T.; Chen, J. S.; Baran, P. S. Convergent Total Synthesis of (+)-Calcipotriol: A Scalable, Modular Approach to Vitamin D Analogs. PNAS, 2022, 119, e2200814119
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240. Harwood, S. J.; Palkowitz, M. D.; Gannet, C. N.; Perez, P.; Yao, Z.; Sun, L.; Abruna, H. D.; Anderson, S. L.; Baran, P. S. Modular Terpene Synthesis Enabled by Mild Electrochemical Couplings. Science 2022, 375, 745 - 752
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239. Knouse, K. W.; Flood, D. T.; Vantourout, J. C.; Schmidt, M. A.: Mcdonald, I. M.; Eastgate, M. D.; Baran, P. S. Nature Chose Phosphates and Chemists Should Too: How Emerging P(V) Methods Can Augment Existing Strategies. ACS Cent. Sci. 2021, 7, 1473 - 1485
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238. Gnaim, S.; Bauer, A.; Zhang, H.-J.; Chen, L.; Gannet, C.; Malapit, C. A.; Hill, D.; Vogt, D.; Tang, Tianhua, T.; Daley, R.; Hao, W.; Quertenmont, M.; Beck, W. D.; Kandahari, E.; Vantourout, J. C.; Echeverria, P.-G.; Abruna, H.; Blackmond, D.; Minteer, S.; Reisman, S.; Sigman, M. S.; Baran, P. S. Cobalt-Electrocatalytic Hydrogen Atom Transfer for Functionalization of Unsaturated C-C Bonds. Nature 2022, 605, 687
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237. Ociepa, M.; Knouse, K. W.; He. D.; Vantourout, J. C.; Flood, D. T.; Padial, N. M.; Chen, J. S.; Sanchez, B. B.; Sturgell, E. J.; Zheng, B.; Qiu, S.; Schmidt, M. A.; Eastgate, M. D.; Baran, P. S. Mild and Chemoselective Phorsphorylation of Alcohols Using a Psi-Reagent. Org. Lett. 2021, 23, 9337 - 9342
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236. Zhang, H.-J.; Chen, L.; Oderinde, M. S.; Edwards, J. T.; Kawamata, Y.; Baran, P. S. Chemoselective, Scalable Nickel-Electrocatalytic O-Arylation of Alcohols. Angew. Chem. Int. Ed. 2021, 60, 20700 - 20705
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235. Choi, J.; Laudadio, G.; Godineau, E.; Baran. P. S. Practical and Regioselective Synthesis of C4-Alkylated Pyridines. J. Am. Chem. Soc. 2021, 143, 11927 - 11933
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234. Maity, P.; Anandamurthy, A. S.; Shekarappa, V.; Vaidyanathan, R.; Zheng, B.; Zhu, J.; Schmidt, M. A.; Fox, R. J.; Knouse, K. W.; Vantourout, J. C.; Baran, P. S.; Eastgate, M. D. Synthesis of a Phosphorous Sulfur Incorporating Reagent for the Enantioselective Synthesis of Thiophosphates. Org. Synth. 2021, 98, 97-116
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233. Huang, Y.; Knouse, K. W.; Qiu, S.; Hao, W.; Padial, N. M.; Vantourout, J. C.; Zheng, B.; Mercer, S. E.; Lopez, J. O.; Narayan, R.; Olson, R. E.; Blackmond, D. G.; Eastgate, M. D.; Schmidt, M. A.; McDonald, I. M.; Baran, P. S. A P(V)-Platform for Oligonucleotide Synthesis. Science, 2021, 373, 1265 - 1270
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232. Kawamata, Y.; Hayashi, K.; Carlson, E.; Shaji, S.; Waldmann, D.; Simmons, B. J.; Edwards, J.; Zapf, C. W.; Saito, M.; Baran, P. S. Chemoselective Electrosynthesis Using Rapid Alternating Polarity. J. Am. Chem. Soc. 2021, 143, 16580 - 16588
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231. Gao, Y.; Hill, D. E.; Hao, W.; McNicolas, B. J.; Vantourout, J. C.; Hadt, R. G.; Reisman, S. E.; Blackmond, D.; Baran, P. S. Electrochemical Nozaki–Hiyama–Kishi Coupling: Scope, Applications, and Mechanism. J. Am. Chem. Soc. 2021, 143, 9478 - 9488
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230. Barton, L. M.; Chen, L.; Blackmond, D.; Baran, P. S. Electrochemical Borylation of Carboxylic Acids. PNAS, 2021, 118, e2109408118
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229. Saito, M.; Kawamata, Y.; Meanwell, M.; Navratil, R.; Chiodi, D.; Carlson, E.; Hu, P.; Chen, L.; Udyavara, S.; Kingston, C.; Tanwar, M.; Tyagi, S.; McKillan, B. P.; Gichina, M. G.; Schmidt, M. A.; Eastgate, M. D.; Lamberto, M.; He, C.; Tang, T.; Malapit, C.; Sigman, M. S.; Minteer, S. D.; Neurock, M.; Baran, P. S. N-Ammonium Ylide Mediators for Electrochemical C–H Oxidation. J. Am. Chem. Soc. 2021, 143, 7859 - 7867
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228. Peters, D. S.; Pitts, C. R.; McClymont, K. S.; Stratton, T. P.; Bi, C.; Baran, P. S. Ideality in Context: Motivations for Total Synthesis. Acc. Chem. Res. 2021, 54, 605 - 617
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227. Gnaim, S.; Vantourout, J. C.; Serpier, F.; Echeverria, P.-G.; Baran, P. S. Carbonyl Desaturation: Where Does Catalysis Stand? ACS Catal. 2021, 11, 883 - 892